Naringenin/flavonoid sensor (FdeR + CRISPRa)

Detects naringenin and related flavonoids (dietary and nutraceutical compounds). The Marionette FdeR sensor gates a CRISPRa circuit driving a fluorescent reporter, in the food-grade GRAS chassis Lactococcus lactis.

Chemical / metaboliteBSL-1 chassisGRAStemplatenaringeninflavonoidnutraceuticalfoodchemicalMarionetteGRASCRISPRa
Input
Naringenin (flavonoid)
Chemical / metabolite
Sense
CRISPRa-activation
dCas9-ω (CRISPRa activator)
Chassis
Lactococcus lactis (MG1363)
BSL-1
Output
mCherry
fluorescent

What it detects

Analyte
Naringenin (flavonoid) — FdeR responds across µM naringenin
Category
Chemical / metabolite
Signal
Naringenin/flavonoids in food, beverages, and fermentation

Genetic circuit

⤢ click to enlarge

Genetic construct (SBOL)

The DNA construct as transcription units, drawn with SBOL Visual part glyphs.

⤢ click to enlarge

CRISPR sensing mechanism

Strategy
CRISPRa-activation · amplifier logic
Cas protein
dCas9-ω (CRISPRa activator)
Analyte sensor
FdeR (LysR family) activates its promoter on binding naringenin.
Signal flow
Naringenin -> FdeR activates PfdeA -> transcribes an sgRNA -> dCas9-activator amplifies a fluorescent reporter (CRISPRa) -> fluorescence rises with naringenin.

Safe chassis

Lactococcus lactis (MG1363)Lactococcus lactis

Food-grade, GRAS lactic acid bacterium used for centuries in dairy fermentation. Non-colonizing and ideal for ingestible / clinical biosensors where a food-safe, gut-transient host is wanted.

BSL-1GRAS · FDA GRAS for food useprobiotic

Genetic parts

PartRoleSource / id
FdeR regulator
Naringenin-responsive LysR-family activator.
regulatorMarionette sensor (Meyer et al. 2019); Herbaspirillum fde system
PfdeA promoter
Activated by naringenin-bound FdeR.
promoterfde operon promoter
Reporter-activating sgRNAsgRNAdesigned for CRISPRa upstream of a weak reporter promoter
sgRNA scaffold (SpCas9)
GTTTTAGAGCTAGAAATAGCAAGTTAAAATAAGGCTAGTCCGTTATCAACTTGAAAAAGTGGCACCGAGTCGGTGC
sgRNAStandard SpCas9 scaffold
dCas9-ω activatordCas9Bikard et al. 2013 (CRISPRa)
mCherry reporterreporterstandard fluorophore

Output & readout

Type
fluorescent
Reporter
mCherry
Readout
Fluorescence (plate reader)
Positive result
Fluorescence increases with naringenin.

Performance

Limit of detection
FdeR Marionette sensor: µM naringenin (module-validated).
Dynamic range
~1-100 µM naringenin
Response time
~180 min
Device validated
No — design template (parts validated individually)

FdeR is a characterised orthogonal Marionette sensor; integrated CRISPRa device is a design template (requires porting to L. lactis).

Safety

Biosafety level
BSL-1 (non-pathogenic chassis)
GRAS chassis
Yes
Biocontainment
thyA-based containment in L. lactis; food-grade host.
Field-deployable
Lab / supervised use

GRAS / food-grade chassis; suited to food and nutraceutical screening.

Build & run

#StageStep
1designPort + design
Codon-optimise FdeR/PfdeA for L. lactis; design the CRISPRa sgRNA.
2assemblyAssemble units
TU1: FdeR + PfdeA -> sgRNA. TU2: dCas9-omega. TU3: weak promoter -> mCherry. NICE vectors.
3transformationTransform L. lactis MG1363
Electroporate; select; add thyA containment.
4inductionExpose to sample
Add food sample + naringenin standard curve.
5readoutMeasure fluorescence
Interpolate naringenin from the curve.

Source & parts

Design
Design template combining the Marionette FdeR naringenin sensor with L. lactis CRISPRa
Parts validated in
  • Meyer et al. 2019, Nat. Chem. Biol. (Marionette sensors, FdeR)
  • Bikard et al. 2013, NAR (CRISPRa)
License
Parts per their original sources; design template CC BY 4.0