Vanillate sensor (VanR + CRISPRa)

Detects vanillate/vanillin (lignin-degradation and food/flavour marker). The Marionette VanR sensor gates a CRISPRa circuit driving a fluorescent reporter, in safe E. coli K-12.

Chemical / metaboliteBSL-1 chassistemplatevanillatevanillinligninfoodchemicalMarionetteCRISPRa
Input
Vanillic acid / vanillin
Chemical / metabolite
Sense
CRISPRa-activation
dCas9-ω (CRISPRa activator)
Chassis
E. coli K-12 (MG1655)
BSL-1
Output
sfGFP
fluorescent

What it detects

Analyte
Vanillic acid / vanillin — VanR responds across µM vanillate
Category
Chemical / metabolite
Signal
Vanillate in lignin-processing streams, food, and fermentation

Genetic circuit

⤢ click to enlarge

Genetic construct (SBOL)

The DNA construct as transcription units, drawn with SBOL Visual part glyphs.

⤢ click to enlarge

CRISPR sensing mechanism

Strategy
CRISPRa-activation · amplifier logic
Cas protein
dCas9-ω (CRISPRa activator)
Analyte sensor
VanR de-represses the Pvan promoter on binding vanillate.
Signal flow
Vanillate -> VanR releases Pvan -> transcribes an sgRNA -> dCas9-activator amplifies a fluorescent reporter (CRISPRa) -> fluorescence rises with vanillate.

Safe chassis

E. coli K-12 (MG1655)Escherichia coli

The non-pathogenic laboratory workhorse. K-12 strains have lost the ability to colonize the human gut and are the reference BSL-1 host for genetic engineering, with the deepest tooling of any bacterial chassis.

BSL-1

Genetic parts

PartRoleSource / id
VanR regulator
Vanillate-responsive repressor, characterised as an orthogonal Marionette sensor.
regulatorMarionette sensor (Meyer et al. 2019); Caulobacter van system
Pvan promoter
De-repressed by vanillate-bound VanR.
promotervan operon promoter
Reporter-activating sgRNAsgRNAdesigned for CRISPRa upstream of a weak reporter promoter
sgRNA scaffold (SpCas9)
GTTTTAGAGCTAGAAATAGCAAGTTAAAATAAGGCTAGTCCGTTATCAACTTGAAAAAGTGGCACCGAGTCGGTGC
sgRNAStandard SpCas9 scaffold
dCas9-ω activatordCas9Bikard et al. 2013 (CRISPRa)
sfGFPreporterPedelacq et al. 2006

Output & readout

Type
fluorescent
Reporter
sfGFP
Readout
Green fluorescence (plate reader)
Positive result
Fluorescence increases with vanillate.

Performance

Limit of detection
VanR Marionette sensor: µM vanillate (module-validated).
Dynamic range
~1-100 µM vanillate
Response time
~150 min
Device validated
No — design template (parts validated individually)

VanR is a characterised orthogonal Marionette sensor; integrated CRISPRa device is a design template.

Safety

Biosafety level
BSL-1 (non-pathogenic chassis)
GRAS chassis
No
Biocontainment
Lab/contained; add kill-switch for field use.
Field-deployable
Lab / supervised use

E. coli K-12 non-pathogenic BSL-1 host.

Build & run

#StageStep
1designDesign CRISPRa sgRNA
Target a weak reporter promoter; check host off-targets.
2assemblyAssemble units
TU1: VanR + Pvan -> sgRNA. TU2: dCas9-omega. TU3: weak promoter -> sfGFP.
3transformationTransform E. coli K-12
Select; confirm vanillate-dependent activation.
4inductionExpose to sample
Add sample + vanillate standard curve.
5readoutMeasure fluorescence
Interpolate vanillate from the curve.

Source & parts

Design
Design template combining the Marionette VanR vanillate sensor with E. coli CRISPRa
Parts validated in
  • Meyer et al. 2019, Nat. Chem. Biol. (Marionette sensors, VanR)
  • Bikard et al. 2013, NAR (CRISPRa)
License
Parts per their original sources; design template CC BY 4.0