Salicylate sensor (NahR + CRISPRi)

Detects salicylate (a naphthalene-degradation marker and drug metabolite). The NahR LysR-family activator gates a CRISPRi circuit driving a visible pigment, in safe E. coli K-12.

Environmental contaminantBSL-1 chassistemplatesalicylatenaphthalenepollutantchemicalenvironmentalCRISPRichromoprotein
Input
Salicylate
Environmental contaminant
Sense
CRISPRi-repression
dCas9 (S. pyogenes, catalytically dead)
Chassis
E. coli K-12 (MG1655)
BSL-1
Output
amilCP
pigment

What it detects

Analyte
Salicylate — NahR responds across µM salicylate
Category
Environmental contaminant
Signal
Salicylate in water (naphthalene/PAH degradation intermediate; also a drug metabolite)

Genetic circuit

⤢ click to enlarge

Genetic construct (SBOL)

The DNA construct as transcription units, drawn with SBOL Visual part glyphs.

⤢ click to enlarge

CRISPR sensing mechanism

Strategy
CRISPRi-repression · NOT logic
Cas protein
dCas9 (S. pyogenes, catalytically dead)
Analyte sensor
NahR (LysR family) binds salicylate and activates the Psal/Pnah promoters.
Signal flow
Salicylate -> NahR activates Psal -> transcribes an anti-pigment sgRNA -> CRISPRi represses a constitutive amilCP cassette -> pigment fades with salicylate (NOT). Pair an inverter for colour-on.

Safe chassis

E. coli K-12 (MG1655)Escherichia coli

The non-pathogenic laboratory workhorse. K-12 strains have lost the ability to colonize the human gut and are the reference BSL-1 host for genetic engineering, with the deepest tooling of any bacterial chassis.

BSL-1

Genetic parts

PartRoleSource / id
NahR regulator
Salicylate-responsive activator.
regulatorPseudomonas NAH7 plasmid (LysR family)
Psal promoter
Activated by salicylate-bound NahR.
promoterNAH7 sal operon promoter
Anti-pigment sgRNAsgRNAdesigned against the amilCP promoter
sgRNA scaffold (SpCas9)
GTTTTAGAGCTAGAAATAGCAAGTTAAAATAAGGCTAGTCCGTTATCAACTTGAAAAAGTGGCACCGAGTCGGTGC
sgRNAStandard SpCas9 scaffold
dCas9dCas9Qi et al. 2013 (CRISPRi)
amilCP chromoproteinreporterBBa_K592009

Output & readout

Type
pigment
Reporter
amilCP
Readout
Visible pigment (naked eye / smartphone)
Positive result
Pigment change reports salicylate.

Performance

Limit of detection
NahR module: µM salicylate (module-validated).
Dynamic range
~1-100 µM salicylate
Response time
~180 min
Device validated
No — design template (parts validated individually)

NahR is a classic, well-characterised salicylate sensor; integrated CRISPRi device is a design template.

Safety

Biosafety level
BSL-1 (non-pathogenic chassis)
GRAS chassis
No
Biocontainment
Lab/contained; add kill-switch for field use.
Field-deployable
Yes (with containment)

Instrument-free pigment readout.

Build & run

#StageStep
1designDesign anti-pigment sgRNA
Target the amilCP promoter; check host off-targets.
2assemblyAssemble units
TU1: NahR + Psal -> sgRNA. TU2: dCas9 + constitutive amilCP.
3transformationTransform E. coli K-12
Select; confirm baseline pigment without salicylate.
4inductionExpose to sample
Add sample + salicylate standard curve.
5readoutScore colour
Compare pigment to the curve.

Source & parts

Design
Design template combining the NahR salicylate-sensing module with E. coli CRISPRi
Parts validated in
  • Schell / NahR salicylate regulation (NAH7)
  • Qi et al. 2013, Cell (CRISPRi)
License
Parts per their original sources; design template CC BY 4.0