Phosphate sensor (PhoPR + CRISPRa)

Reports phosphate status (relevant to water-quality and eutrophication monitoring). The native B. subtilis PhoP/PhoR phosphate-starvation system gates a CRISPRa circuit driving a fluorescent reporter, in spore-forming Bacillus subtilis 168.

Chemical / metaboliteBSL-1 chassisGRAStemplatephosphatewater-qualityeutrophicationchemicalCRISPRaspore
Input
Inorganic phosphate (Pi)
Chemical / metabolite
Sense
CRISPRa-activation
dCas9-ω (CRISPRa activator)
Chassis
Bacillus subtilis 168
BSL-1
Output
sfGFP
fluorescent

What it detects

Analyte
Inorganic phosphate (Pi) — PhoPR responds across phosphate-limited to -replete transition
Category
Chemical / metabolite
Signal
Phosphate availability in water/soil (low-phosphate triggers the Pho response)

Genetic circuit

⤢ click to enlarge

Genetic construct (SBOL)

The DNA construct as transcription units, drawn with SBOL Visual part glyphs.

⤢ click to enlarge

CRISPR sensing mechanism

Strategy
CRISPRa-activation · amplifier logic
Cas protein
dCas9-ω (CRISPRa activator)
Analyte sensor
Under phosphate limitation the PhoR sensor kinase phosphorylates PhoP, which activates Pho-regulon promoters (e.g. PphoA/Ppst).
Signal flow
Low Pi -> PhoR/PhoP activates a Pho promoter -> transcribes an sgRNA -> dCas9-activator amplifies a fluorescent reporter (CRISPRa) -> fluorescence reports phosphate-starvation state.

Safe chassis

Bacillus subtilis 168Bacillus subtilis

Gram-positive, spore-forming model bacterium with QPS (EFSA) status and a long history of safe industrial use. Spores make it robust for field-deployable and environmental biosensors.

BSL-1GRAS · EFSA Qualified Presumption of Safety (QPS)

Genetic parts

PartRoleSource / id
PhoP/PhoR two-component system
Phosphate-starvation sensor; endogenous to B. subtilis.
regulatorNative B. subtilis pho regulon
Pho-regulon promoter (e.g. PphoA)
Activated by phospho-PhoP under low phosphate.
promoterB. subtilis phoA/pst promoter
Reporter-activating sgRNAsgRNAdesigned for CRISPRa upstream of a weak reporter promoter
sgRNA scaffold (SpCas9)
GTTTTAGAGCTAGAAATAGCAAGTTAAAATAAGGCTAGTCCGTTATCAACTTGAAAAAGTGGCACCGAGTCGGTGC
sgRNAStandard SpCas9 scaffold
dCas9-ω activatordCas9Bikard et al. 2013 (CRISPRa)
sfGFPreporterPedelacq et al. 2006

Output & readout

Type
fluorescent
Reporter
sfGFP
Readout
Green fluorescence (field fluorimeter)
Positive result
Fluorescence reflects phosphate-starvation signalling.

Performance

Limit of detection
PhoPR module reports the phosphate-limited transition (module-validated).
Dynamic range
Phosphate-limited to -replete transition
Response time
~180 min
Device validated
No — design template (parts validated individually)

Reports phosphate status (inverse to abundance); integrated CRISPRa device is a design template. Best used as a relative phosphate-status reporter.

Safety

Biosafety level
BSL-1 (non-pathogenic chassis)
GRAS chassis
Yes
Biocontainment
GRAS, spore-forming host; auxotrophic/spore containment.
Field-deployable
Yes (with containment)

Spores allow ambient storage; relevant to surface-water eutrophication surveys.

Build & run

#StageStep
1designDesign CRISPRa sgRNA
Target the activation window of a weak reporter promoter; check B. subtilis off-targets.
2assemblyAssemble units
TU1: Pho promoter -> sgRNA (native PhoPR). TU2: dCas9-omega. TU3: weak promoter -> sfGFP. Integrate at amyE/thrC.
3transformationTransform B. subtilis 168
Use natural competence; select; calibrate vs phosphate-replete/limited media.
4inductionExpose to sample
Reconstitute spores; add sample + phosphate standard curve.
5readoutMeasure fluorescence
Interpolate relative phosphate from the curve.

Source & parts

Design
Design template combining the native B. subtilis PhoPR phosphate system with CRISPRa
Parts validated in
  • Hulett et al. / B. subtilis Pho regulon (PhoP/PhoR) literature
  • Bikard et al. 2013, NAR (CRISPRa)
License
Parts per their original sources; design template CC BY 4.0