Lead water sensor (PbrR + CRISPRi)

Detects lead Pb(II) in water. The PbrR metal-responsive regulator gates a CRISPRi circuit driving sfGFP, in spore-forming Bacillus subtilis 168 for rugged, field-storable testing.

Environmental contaminantBSL-1 chassisGRAStemplateleadheavy-metalwaterenvironmentalCRISPRisporefield
Input
Lead Pb(II)
Environmental contaminant
Sense
CRISPRi-repression
dCas9 (S. pyogenes, catalytically dead)
Chassis
Bacillus subtilis 168
BSL-1
Output
sfGFP
fluorescent

What it detects

Analyte
Lead Pb(II) — PbrR sensors respond from sub-µM to µM Pb(II); aim below the 10 µg/L (~0.05 µM) WHO/EPA action level
Category
Environmental contaminant
Signal
Bioavailable inorganic lead in drinking water

Genetic circuit

⤢ click to enlarge

Genetic construct (SBOL)

The DNA construct as transcription units, drawn with SBOL Visual part glyphs.

⤢ click to enlarge

CRISPR sensing mechanism

Strategy
CRISPRi-repression · NOT logic
Cas protein
dCas9 (S. pyogenes, catalytically dead)
Analyte sensor
PbrR (a MerR-family regulator) binds Pb(II) and activates the pbr promoter.
Signal flow
Pb(II) -> PbrR activates Ppbr -> transcribes an anti-reporter sgRNA -> dCas9 + sgRNA repress a constitutive sfGFP cassette (CRISPRi) -> fluorescence inverts with lead. Pair a second inverter for turn-on output.

Safe chassis

Bacillus subtilis 168Bacillus subtilis

Gram-positive, spore-forming model bacterium with QPS (EFSA) status and a long history of safe industrial use. Spores make it robust for field-deployable and environmental biosensors.

BSL-1GRAS · EFSA Qualified Presumption of Safety (QPS)

Genetic parts

PartRoleSource / id
PbrR regulator
Lead-responsive MerR-family activator; may require codon-optimisation for B. subtilis.
regulatorCupriavidus metallidurans pbr operon
Ppbr promoter
Activated by Pb(II)-bound PbrR.
promoterC. metallidurans pbr operator/promoter
Anti-reporter sgRNA
Transcribed from Ppbr.
sgRNAdesigned against the sfGFP promoter
sgRNA scaffold (SpCas9)
GTTTTAGAGCTAGAAATAGCAAGTTAAAATAAGGCTAGTCCGTTATCAACTTGAAAAAGTGGCACCGAGTCGGTGC
sgRNAStandard SpCas9 scaffold
dCas9
CRISPRi is validated in B. subtilis.
dCas9Peters et al. 2016 (CRISPRi in B. subtilis)
Pveg promoter
Drives the sfGFP reporter (CRISPRi target).
promoterB. subtilis vegetative promoter
sfGFPreporterPedelacq et al. 2006

Output & readout

Type
fluorescent
Reporter
sfGFP
Readout
Green fluorescence (field fluorimeter)
Positive result
Fluorescence change scales with lead concentration.

Performance

Limit of detection
PbrR module: sub-µM Pb(II) (module-validated).
Dynamic range
~0.05-5 µM Pb(II)
Response time
~150 min
Device validated
No — design template (parts validated individually)

PbrR lead sensors and B. subtilis CRISPRi are validated separately; integrated device is a design template. Spores allow ambient-temperature storage and reconstitution in the field.

Safety

Biosafety level
BSL-1 (non-pathogenic chassis)
GRAS chassis
Yes
Biocontainment
B. subtilis is contained via auxotrophy/spore control; GRAS host.
Field-deployable
Yes (with containment)

GRAS, spore-forming chassis well suited to low-resource field deployment.

Build & run

#StageStep
1designDesign anti-reporter sgRNA
Target the sfGFP promoter; check B. subtilis off-targets.
2assemblyAssemble units
TU1: PbrR. TU2: Ppbr -> sgRNA. TU3: dCas9 + Pveg -> sfGFP. Integrate at amyE/thrC loci.
3transformationTransform B. subtilis 168
Use natural competence; select integrants; confirm low background.
4inductionExpose to sample
Reconstitute spores, add water sample + lead standard curve.
5readoutMeasure fluorescence
Interpolate Pb(II) from the standard curve.

Source & parts

Design
Design template combining a PbrR lead-sensing module with B. subtilis CRISPRi
Parts validated in
  • Borremans et al. 2001 (pbr lead resistance/sensing, C. metallidurans)
  • Peters et al. 2016, Cell (CRISPRi in B. subtilis)
License
Parts per their original sources; design template CC BY 4.0