Cuminate sensor (CymR + CRISPRa)

Detects cuminate (p-isopropylbenzoate), a terpenoid-degradation marker. The native P. putida CymR sensor gates a CRISPRa circuit driving a fluorescent reporter, in P. putida KT2440.

Chemical / metaboliteBSL-1 chassistemplatecuminatecumateterpenoidchemicalMarionetteCRISPRa
Input
Cuminate (p-isopropylbenzoate) / cumate
Chemical / metabolite
Sense
CRISPRa-activation
dCas9-ω (CRISPRa activator)
Chassis
Pseudomonas putida KT2440
BSL-1
Output
sfGFP
fluorescent

What it detects

Analyte
Cuminate (p-isopropylbenzoate) / cumate — CymR responds across µM cumate
Category
Chemical / metabolite
Signal
Cuminate/cumate in degradation streams and as a process marker

Genetic circuit

⤢ click to enlarge

Genetic construct (SBOL)

The DNA construct as transcription units, drawn with SBOL Visual part glyphs.

⤢ click to enlarge

CRISPR sensing mechanism

Strategy
CRISPRa-activation · amplifier logic
Cas protein
dCas9-ω (CRISPRa activator)
Analyte sensor
CymR de-represses the Pcym/Pcmt promoter on binding cumate.
Signal flow
Cumate -> CymR releases Pcym -> transcribes an sgRNA -> dCas9-activator amplifies a fluorescent reporter (CRISPRa) -> fluorescence rises with cuminate.

Safe chassis

Pseudomonas putida KT2440Pseudomonas putida

A certified safety-strain soil bacterium with exceptional solvent/stress tolerance and diverse metabolism. The premier chassis for environmental biosensing of pollutants and heavy metals in soil and water.

BSL-1

Genetic parts

PartRoleSource / id
CymR regulator
Cumate-responsive repressor; endogenous to P. putida.
regulatorNative P. putida cym/cmt operon (also a Marionette sensor)
Pcym promoter
De-repressed by cumate-bound CymR.
promoterP. putida cym operon promoter
Reporter-activating sgRNAsgRNAdesigned for CRISPRa upstream of a weak reporter promoter
sgRNA scaffold (SpCas9)
GTTTTAGAGCTAGAAATAGCAAGTTAAAATAAGGCTAGTCCGTTATCAACTTGAAAAAGTGGCACCGAGTCGGTGC
sgRNAStandard SpCas9 scaffold
dCas9-ω activatordCas9Bikard et al. 2013 (CRISPRa)
sfGFPreporterPedelacq et al. 2006

Output & readout

Type
fluorescent
Reporter
sfGFP
Readout
Green fluorescence (plate reader)
Positive result
Fluorescence increases with cuminate.

Performance

Limit of detection
CymR module: µM cumate (module-validated).
Dynamic range
~1-100 µM cumate
Response time
~150 min
Device validated
No — design template (parts validated individually)

CymR is native to P. putida and a characterised Marionette sensor; integrated CRISPRa device is a design template.

Safety

Biosafety level
BSL-1 (non-pathogenic chassis)
GRAS chassis
No
Biocontainment
P. putida KT2440 certified HV1 safety host; add containment for field use.
Field-deployable
Yes (with containment)

Native sensor in the host — minimal porting needed.

Build & run

#StageStep
1designDesign CRISPRa sgRNA
Target a weak reporter promoter; check host off-targets.
2assemblyAssemble units
TU1: Pcym -> sgRNA (native CymR). TU2: dCas9-omega. TU3: weak promoter -> sfGFP. SEVA vectors.
3transformationTransform P. putida KT2440
Electroporate; select; confirm cumate-dependent activation.
4inductionExpose to sample
Add sample + cumate standard curve.
5readoutMeasure fluorescence
Interpolate cuminate from the curve.

Source & parts

Design
Design template combining the native P. putida CymR cumate sensor with CRISPRa
Parts validated in
  • Eaton / P. putida cym-cmt cumate regulation; Meyer et al. 2019 (Marionette CymR)
  • Bikard et al. 2013, NAR (CRISPRa)
License
Parts per their original sources; design template CC BY 4.0