Benzoate sensor (BenM + CRISPRi)

Detects benzoate, a common aromatic pollutant and degradation intermediate. The BenM LysR-family regulator gates a CRISPRi circuit driving a visible pigment, in P. putida KT2440.

Environmental contaminantBSL-1 chassistemplatebenzoatearomaticpollutantsoilwaterenvironmentalCRISPRi
Input
Benzoate
Environmental contaminant
Sense
CRISPRi-repression
dCas9 (S. pyogenes, catalytically dead)
Chassis
Pseudomonas putida KT2440
BSL-1
Output
amilCP
pigment

What it detects

Analyte
Benzoate — BenM responds across µM benzoate / cis,cis-muconate
Category
Environmental contaminant
Signal
Benzoate in soil/water (aromatic-compound degradation marker)

Genetic circuit

⤢ click to enlarge

Genetic construct (SBOL)

The DNA construct as transcription units, drawn with SBOL Visual part glyphs.

⤢ click to enlarge

CRISPR sensing mechanism

Strategy
CRISPRi-repression · NOT logic
Cas protein
dCas9 (S. pyogenes, catalytically dead)
Analyte sensor
BenM (LysR family) activates the benABC promoter in response to benzoate and its metabolite cis,cis-muconate.
Signal flow
Benzoate -> BenM activates PbenA -> transcribes an anti-pigment sgRNA -> CRISPRi represses a constitutive amilCP cassette -> pigment fades with benzoate (NOT). Pair an inverter for colour-on.

Safe chassis

Pseudomonas putida KT2440Pseudomonas putida

A certified safety-strain soil bacterium with exceptional solvent/stress tolerance and diverse metabolism. The premier chassis for environmental biosensing of pollutants and heavy metals in soil and water.

BSL-1

Genetic parts

PartRoleSource / id
BenM regulator
Benzoate/cis,cis-muconate-responsive activator.
regulatorAcinetobacter baylyi ben operon (LysR family)
PbenA promoter
Activated by effector-bound BenM.
promoterben operon promoter
Anti-pigment sgRNAsgRNAdesigned against the amilCP promoter
sgRNA scaffold (SpCas9)
GTTTTAGAGCTAGAAATAGCAAGTTAAAATAAGGCTAGTCCGTTATCAACTTGAAAAAGTGGCACCGAGTCGGTGC
sgRNAStandard SpCas9 scaffold
dCas9dCas9CRISPRi (established in P. putida)
amilCP chromoproteinreporterBBa_K592009

Output & readout

Type
pigment
Reporter
amilCP
Readout
Visible pigment (naked eye / smartphone)
Positive result
Pigment change reports benzoate.

Performance

Limit of detection
BenM module: µM benzoate (module-validated).
Dynamic range
~1-100 µM benzoate
Response time
~180 min
Device validated
No — design template (parts validated individually)

BenM is a well-studied aromatic sensor; integrated CRISPRi device is a design template.

Safety

Biosafety level
BSL-1 (non-pathogenic chassis)
GRAS chassis
No
Biocontainment
P. putida KT2440 certified HV1 safety host; add containment for field use.
Field-deployable
Yes (with containment)

Aromatic-tolerant chassis; instrument-free readout.

Build & run

#StageStep
1designDesign anti-pigment sgRNA
Target the amilCP promoter; check host off-targets.
2assemblyAssemble units
TU1: BenM + PbenA -> sgRNA. TU2: dCas9 + constitutive amilCP. SEVA vectors.
3transformationTransform P. putida KT2440
Electroporate; select; confirm baseline pigment without benzoate.
4inductionExpose to sample
Add soil eluate/water + benzoate standard curve.
5readoutScore colour
Compare pigment to the curve.

Source & parts

Design
Design template combining the BenM benzoate-sensing module with P. putida CRISPRi
Parts validated in
  • Collier/Neidle / BenM benzoate regulation (Acinetobacter baylyi)
  • Qi et al. 2013, Cell (CRISPRi)
License
Parts per their original sources; design template CC BY 4.0