Alkane/oil sensor (AlkS + CRISPRa)

Detects medium-chain alkanes (diesel / crude-oil contamination). The AlkS regulator gates a CRISPRa circuit driving a fluorescent reporter, in the solvent-tolerant chassis P. putida KT2440.

Environmental contaminantBSL-1 chassistemplatealkaneoildieselhydrocarbonpollutantsoilwaterenvironmentalCRISPRa
Input
Medium-chain alkanes (e.g. octane)
Environmental contaminant
Sense
CRISPRa-activation
dCas9-ω (CRISPRa activator)
Chassis
Pseudomonas putida KT2440
BSL-1
Output
sfGFP
fluorescent

What it detects

Analyte
Medium-chain alkanes (e.g. octane) — AlkS/PalkB responds across µM alkane
Category
Environmental contaminant
Signal
Alkane/oil contamination in soil and water (spill monitoring)

Genetic circuit

⤢ click to enlarge

Genetic construct (SBOL)

The DNA construct as transcription units, drawn with SBOL Visual part glyphs.

⤢ click to enlarge

CRISPR sensing mechanism

Strategy
CRISPRa-activation · amplifier logic
Cas protein
dCas9-ω (CRISPRa activator)
Analyte sensor
AlkS binds alkanes and activates the PalkB promoter of the alkane-degradation operon.
Signal flow
Alkane -> AlkS activates PalkB -> transcribes an sgRNA -> dCas9-activator amplifies a fluorescent reporter (CRISPRa) -> fluorescence rises with hydrocarbon contamination.

Safe chassis

Pseudomonas putida KT2440Pseudomonas putida

A certified safety-strain soil bacterium with exceptional solvent/stress tolerance and diverse metabolism. The premier chassis for environmental biosensing of pollutants and heavy metals in soil and water.

BSL-1

Genetic parts

PartRoleSource / id
AlkS regulator
Alkane-responsive activator.
regulatorPseudomonas putida/oleovorans OCT plasmid alk operon
PalkB promoter
Activated by alkane-bound AlkS.
promoteralk operon promoter
Reporter-activating sgRNAsgRNAdesigned for CRISPRa upstream of a weak reporter promoter
sgRNA scaffold (SpCas9)
GTTTTAGAGCTAGAAATAGCAAGTTAAAATAAGGCTAGTCCGTTATCAACTTGAAAAAGTGGCACCGAGTCGGTGC
sgRNAStandard SpCas9 scaffold
dCas9-ω activatordCas9Bikard et al. 2013 (CRISPRa)
sfGFPreporterPedelacq et al. 2006

Output & readout

Type
fluorescent
Reporter
sfGFP
Readout
Green fluorescence (field fluorimeter)
Positive result
Fluorescence increases with alkane/oil contamination.

Performance

Limit of detection
AlkS/PalkB module: µM alkane (module-validated).
Dynamic range
~1-100 µM alkane
Response time
~180 min
Device validated
No — design template (parts validated individually)

AlkS is a classic alkane sensor and PalkB a widely used inducible promoter; integrated CRISPRa device is a design template. P. putida natively tolerates solvents.

Safety

Biosafety level
BSL-1 (non-pathogenic chassis)
GRAS chassis
No
Biocontainment
P. putida KT2440 certified HV1 safety host; add containment for field use.
Field-deployable
Yes (with containment)

Solvent-tolerant chassis suited to spill sites.

Build & run

#StageStep
1designDesign CRISPRa sgRNA
Target a weak reporter promoter; check host off-targets.
2assemblyAssemble units
TU1: AlkS + PalkB -> sgRNA. TU2: dCas9-omega. TU3: weak promoter -> sfGFP. SEVA vectors.
3transformationTransform P. putida KT2440
Electroporate; select; confirm alkane-dependent activation.
4inductionExpose to sample
Add soil eluate/water + alkane standard curve.
5readoutMeasure fluorescence
Interpolate alkane from the curve.

Source & parts

Design
Design template combining the AlkS alkane-sensing module with P. putida CRISPRa
Parts validated in
  • de Lorenzo et al. / AlkS-PalkB alkane regulation (Pseudomonas)
  • Bikard et al. 2013, NAR (CRISPRa)
License
Parts per their original sources; design template CC BY 4.0